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RESEARCH PRODUCT
Modular Access to 9,9-Spirobifluorenes by Oxidative Coupling Using Molybdenum Pentachloride
Siegfried R. WaldvogelDieter SchollmeyerSimon Trosiensubject
chemistry.chemical_classificationChemistryOrganic ChemistryOxidizing agentPolymer chemistryOxidative coupling of methanePolymerBond formationMolybdenum pentachlorideCatalysisdescription
The strong oxidizing agent molybdenum pentachloride was used for an efficient direct C–C bond formation of 9,9-diarylfluorenes to the corresponding 9,9-spirobifluorenes. Thus, a versatile method that is compatible with labile groups, such as iodo moieties, was established. By this approach important building blocks for light emitting polymers were synthesized in high yields.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2013-03-21 | Synthesis |