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RESEARCH PRODUCT
Complexes of organometallic compounds. LI. The correlation between 119Sn Mössbauer isomer shifts and partial atomic charges on tin in R3SnL compounds
Renato BarbieriArturo SilvestriGiuseppe AlonzoGiuseppe Ruisisubject
Inorganic ChemistryElectronegativity equalizationValence (chemistry)ChemistryMössbauer spectroscopyInorganic chemistryMaterials ChemistryPhysical chemistrychemistry.chemical_elementAtomic chargePhysical and Theoretical ChemistryTinGroup 2 organometallic chemistrydescription
Abstract The 119Sn Mossbauer isomer shift parameters, δ, of compounds R3SnL (R = AlK, Ph; L = F, Cl, OH, OR′, CN, NCS, NCO, N3) have been correlated to partial atomic charges on tin QSn, calculated according to a valence state electronegativity equalization procedure carried out by the CHELEQ program. A unique δ/QSn correlation has been obtained for all the five-coordinated R3SnL species by using average δ parameters for the AlK3IV derivatives.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1985-02-01 | Inorganica Chimica Acta |