6533b825fe1ef96bd1281d1c

RESEARCH PRODUCT

Die darstellung von [(CH3)3PRu(CO)2Cl2]2 und [(Ch3)3P]2Ru(CO)2Cl2; Eine berichtigung zu: Die alkoholyse des triethylsilans katalysiert von [(Ch3)3P]2Ru(CO)2Cl2

Hellmut SingerJ. Lippold

subject

DimerOrganic ChemistryTrimethylphosphinechemistry.chemical_elementAlcoholBiochemistryMedicinal chemistryCatalysisRutheniumInorganic Chemistrychemistry.chemical_compoundchemistryMaterials ChemistryOrganic chemistryPhysical and Theoretical ChemistryChemical composition

description

Abstract The ruthenium(II) complex used as a catalyst in reactions of alcohols and Et 3 SiH proved to be the dimer [(CH 3 ) 3 PRu(CO) 2 Cl 2 ] 2 and not the complex [(CH 3 ) 3 P] 2 Ru(CO) 2 Cl 2 . Both complexes were prepared, characterized and their catalytic properties were compared.

https://doi.org/10.1016/0022-328x(84)80116-3