6533b825fe1ef96bd1281f90
RESEARCH PRODUCT
Neutral nido-heteroboranes with non ionisable hydrogen as arenes in coordination
Francesc TeixidorClara ViñasOscar TutusausRaikko KivekäsReijo Sillanpääsubject
Hydrogen010405 organic chemistryHeteroatomMetals and Alloyschemistry.chemical_elementGeneral Chemistry010402 general chemistry01 natural sciencesCombinatorial chemistryCatalysis3. Good health0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialschemistryMaterials ChemistryCeramics and CompositesOrganic chemistrydescription
Designed ligands have been synthesised to produce the first arene-like metallacarborane. For arene-like coordination the number of electronegative elements on the coordinating site must be kept to a minimum. Choosing ligands with bulky substituents on the heteroatom allows easy rearrangement and arene-like coordination. This is more hampered the higher the number of hetereoatoms to be re-located.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2003-11-01 | Chem. Commun. |