6533b825fe1ef96bd12827ef
RESEARCH PRODUCT
Synthesis and characterisation of p-block complexes of biquinoline at different ligand charge states
Ian S. MorganJuha HurmalainenAnssi PeuronenAkseli MansikkamäkiHeikki M. Tuononensubject
Inorganic ChemistryCrystallographyTransition metal010405 organic chemistryChemistryLigandCharge (physics)p-block complexes010402 general chemistryBlock (periodic table)01 natural sciencesta1160104 chemical sciencesdescription
The first examples of p-block coordination complexes of biquinoline, namely [(biq)BCl2]Cl and [(biq)BCl2]˙, were synthesized and structurally characterized. The acquired data allowed the estimation of the ligand charge state based on its metrical parameters. The subsequent use of this protocol, augmented with theoretical calculations, revealed ambiguities in the published data for transition metal complexes of biquinoline. peerReviewed
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2017-01-17 | Dalton Transactions |