Enantioselective Hydrogenation Catalysis Aided by a σ-Bonded Calix[4]arene to a P-Chirogenic Aminophosphane Phosphinite Rhodium Complex

6533b826fe1ef96bd1283abc

RESEARCH PRODUCT

Enantioselective Hydrogenation Catalysis Aided by a σ-Bonded Calix[4]arene to a P-Chirogenic Aminophosphane Phosphinite Rhodium Complex

Sylvain Jugé Jérôme Bayardon Etienne Bertrand Etienne Bertrand Yoann Rousselin Marie-joëlle Ondel-eymin Naïma Khiri Pierre D. Harvey

subject

Phosphinite Ligand Organic Chemistry Enantioselective synthesis chemistry.chemical_element Medicinal chemistry Rhodium Inorganic Chemistry chemistry.chemical_compound Hydrogenation catalysis chemistry Moiety Organic chemistry Physical and Theoretical Chemistry

description

The first P-chirogenic aminophosphane−phosphinite (AMP*P) ligand (4a) supported on the upper rim of a calix[4]arene moiety was synthesized in two steps using the ephedrine methodology. Ligand 4a wa...

year	journal	country	edition	language
2010-07-23	Organometallics

https://doi.org/10.1021/om100520u

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