6533b826fe1ef96bd1283f1a
RESEARCH PRODUCT
Oxidative transformation of aryls using molybdenum pentachloride.
Siegfried R. WaldvogelSimon Trosiensubject
Aqueous solutionMetals and Alloyschemistry.chemical_elementGeneral ChemistryOxidative phosphorylationMolybdenum pentachlorideCombinatorial chemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsReaction ratechemistryMolybdenumReagentMaterials ChemistryCeramics and CompositesOrganic chemistryOxidative coupling of methaneLewis acids and basesdescription
Molybdenum pentachloride combines a strong Lewis acid character with an unusually high oxidation potential creating a powerful reagent for oxidative transformations. Since the oxidative coupling reaction of aryls is induced at an extraordinarily high reaction rate, a variety of labile groups, e.g. iodo, tert-alkyl, etc., are tolerated on the aromatic core. Furthermore, the co-formed molybdenum salts can either be exploited for template effects to obtain uncommon geometries in a preferred manner, or redox-play starts after aqueous workup. Therefore MoCl(5) represents a unique and easily available reagent.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2012-07-24 |