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RESEARCH PRODUCT

3-Diazopyrroles—IV. Structure determination using 13C NMR spectroscopy

Anna Maria AlmericoEnrico AielloG. DattoloR. Alan JonesGirolamo Cirrincione

subject

Deuterium NMRCrystallographyChemistryCarbon-13 NMR satelliteGeneral EngineeringAnalytical chemistryNuclear magnetic resonance spectroscopy of nucleic acidsNuclear magnetic resonance crystallographyNuclear magnetic resonance spectroscopyFluorine-19 NMRCarbon-13 NMRTwo-dimensional nuclear magnetic resonance spectroscopy

description

Abstract On the basis of the 13 C NMR chemical shifts, it is proposed that, although b is the major canonical structure, structure c , in which a negative charge resides at C-3, provides an important contribution to the resonance stabilization of the 3-diazopyrroles, 1–4 .

https://doi.org/10.1016/0584-8539(90)80016-r