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RESEARCH PRODUCT
On the Ion-Pair Recognition and Indication Features of a Fluorescent Heteroditopic Host Based on a BODIPY Core
Ana M. CosteroAna M. CosteroKnut RurackRaúl GotorRaúl GotorSalvador GilSalvador GilPablo GaviñaPablo Gaviñasubject
Inorganic saltschemistry.chemical_compound1h nmr spectroscopychemistryOrganic ChemistryExtraction (chemistry)Physical and Theoretical ChemistryIon pairsBODIPYAbsorption (chemistry)PhotochemistryAcetonitrileFluorescencedescription
A fluorescent heteroditopic host for ion pairs and zwitterionic species has been synthesized. Its affinity towards a series of anions, cations and ion pairs in acetonitrile has been assessed, and the spectroscopic response has been evaluated. Solid–liquid extraction experiments of inorganic salts, α-amino acids and γ-aminobutyric acid (GABA) into acetonitrile solutions were performed, and the resulting complexes were analyzed by UV/Vis absorption, fluorescence and 1H NMR spectroscopy. The discrimination patterns observed have been rationalized in terms of the molecular topologies of the host and guests.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2014-05-08 | European Journal of Organic Chemistry |