6533b826fe1ef96bd128491f
RESEARCH PRODUCT
Facile formation of a meso–meso linked porphyrin dimer catalyzed by a manganese(iv)–oxo porphyrin
Atsuro TakaiBenoit HabermeyerShunichi FukuzumiShunichi Fukuzumisubject
MetalloporphyrinsDimerchemistry.chemical_elementManganeseZincPhotochemistryCatalysisCatalysischemistry.chemical_compoundPolymer chemistrypolycyclic compoundsMaterials Chemistryheterocyclic compoundsChemistryfungiMetals and AlloysGeneral ChemistryBond formationPorphyrinSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialscarbohydrates (lipids)Manganese CompoundsRadical ionCatalytic cycleCeramics and CompositesDimerizationdescription
A manganese(IV)-oxo porphyrin catalyzes C-C bond formation between zinc porphyrins at the meso-position with a two-electron oxidant to afford the meso-meso linked porphyrin dimer efficiently. The meso-meso linked dimer is formed via formation of the porphyrin radical cation, and the rate-determining step in the catalytic cycle is the formation of a manganese(IV)-oxo porphyrin with a two-electron oxidant.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2011-05-11 | Chemical Communications |