6533b826fe1ef96bd1285380
RESEARCH PRODUCT
Biphasic dimerisation of methylacrylate--immobilisation and stabilisation of cationic Pd-catalysts in ionic liquids by an ammoniumphosphine ligand.
Igor TkatchenkoStefanie StutzmannPeter WasserscheidJörg Zimmermannsubject
TetrafluoroborateLigandInorganic chemistryMetals and AlloysCationic polymerizationGeneral ChemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCatalysischemistry.chemical_compoundchemistryIonic liquidMaterials ChemistryCeramics and Compositesdescription
The first continuous, biphasic, Pd-catalysed dimerisation of methylacrylate is described. The biphasic system has been realised by using a tetrafluoroborate ionic liquid as catalyst medium and an ammoniumphosphine ligand to immobilise and stabilise the Pd-catalyst.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2002-07-18 | Chemical communications (Cambridge, England) |