6533b827fe1ef96bd12859b0

RESEARCH PRODUCT

Ferroelastic phase transitions of alkali halide-alkali cyanide mixed crystals

K. Knorr

subject

Phase transitionMaterials scienceMechanical EngineeringCyanideInorganic chemistryHalideCondensed Matter PhysicsAlkali metalCondensed Matter::Materials Sciencechemistry.chemical_compoundchemistryMechanics of MaterialsMartensitePhase (matter)Physics::Atomic and Molecular ClustersPhysical chemistryGeneral Materials Science

description

Abstract The alkali cyanides and their CN-rich mixtures with alkali halides are proper ferroelastics with transitions from the cubic high temperature phase into the various non-cubic low temperature phases. As the CN concentration is reduced, the transformations temperature decreases and eventually the ferroelastic low temperature state is suppresse in favour of a glass-like state. The structural and elastic properties of these compounds are discussed with a special emphasis on the martensitic aspect of the transitions.

https://doi.org/10.1016/0921-5093(90)90318-w