Tetracarbonyltungsten(0)-bis(μ-dimethylphosphido)-bis[dicyclopentadienylhydridomolybdenum(IV)]

6533b827fe1ef96bd12859fa

RESEARCH PRODUCT

Tetracarbonyltungsten(0)-bis(μ-dimethylphosphido)-bis[dicyclopentadienylhydridomolybdenum(IV)]

Claude Moïse Marek M. Kubicki Christophe Barre

subject

Chemistry Hydride General Materials Science General Chemistry Condensed Matter Physics Medicinal chemistry Bridge (interpersonal)

description

The title trinuclear WMo2 compound, [Mo2WH2(C5H5)4(C2H6P)2(CO)4], was obtained by opening of the hydride bridge in the dinuclear dibridged (μ-PMe2,H){(C5H5)2Mo}{W(CO)4} complex (MoIV) upon the action of (C5H5)2Mo(PMe2H) (MoII) in THF solution. This involves the formal conversion of MoII to MoIV.

year	journal	country	edition	language
2002-03-22	Acta Crystallographica Section E Structure Reports Online

https://doi.org/10.1107/s1600536802004865

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