A “Cation-less” Oxalate-Based Ferromagnet Formed by Neutral Bimetallic Layers: {[Co(H2O)2]3[Cr(ox)3]2(18-crown-6)2}∞ (ox = Oxalate Dianion; 18-crown-6 = C12H24O6)

6533b827fe1ef96bd12863bc

RESEARCH PRODUCT

A “Cation-less” Oxalate-Based Ferromagnet Formed by Neutral Bimetallic Layers: {[Co(H2O)2]3[Cr(ox)3]2(18-crown-6)2}∞ (ox = Oxalate Dianion; 18-crown-6 = C12H24O6)

Carlos Martí-gastaldo Eugenio Coronado José Ramón Galán-mascarós

subject

Inorganic Chemistry chemistry.chemical_classification chemistry.chemical_compound Crystallography chemistry Ferromagnetism Hydrogen bond 18-Crown-6 Physical and Theoretical Chemistry Bimetallic strip Crown ether Oxalate

description

Neutral layers of the bimetallic oxalate complex {[Co(H2O)2]3[Cr(ox)3]2}∞ are formed in the presence of a crown ether and stabilized by hydrogen bonding. The resulting soluble ferromagnet orders at Tc = 7.4 K.

year	journal	country	edition	language
2007-09-08	Inorganic Chemistry

https://doi.org/10.1021/ic700808h

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