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RESEARCH PRODUCT
Mössbauer studies on tin(IV) and organotin(IV) diacetylbis(benzoylhydrazone) complexes
Nuccio BertazziLorenzo PelleritoG. C. Stoccosubject
DenticityInorganic chemistrychemistry.chemical_elementElectric chargeData treatmentInorganic ChemistryCrystallographyFormalism (philosophy of mathematics)chemistryOctahedronMössbauer spectroscopyMaterials ChemistryPhysical and Theoretical ChemistryTindescription
Abstract The Mossbauer parameters of Ph 2 SnDB, PhClSnDB and Sn(DB) 2 were determined, where DB 2− is the dianion of the multidentate ligand diacetylbis(benzoylhydrazone). According also to data treatment with the point charge model formalism, the configurations of Ph 2 Sn IV and PhSn IV derivatives appear to be essentially octahedral, with linear CSnC and CSnCl skeletons. As to Sn(DB) 2 , it appears that the electrical charge density at the Sn IV nucleus has a cubic symmetry, which is consistent with both tetrahedral and octahedral configurations around Sn IV .
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1974-01-01 | Inorganica Chimica Acta |