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RESEARCH PRODUCT
Photomagnetic effect in a cyanide-bridged mixed-valence {FeII2FeIII2} molecular square
Marie-laure BoillotMannan SeuleimanRodrigue LescouëzecYanling LiMiguel JulveEric RivièreLionel RechignatAbhishake MondalAzzedine BousseksouPatrick Hersonsubject
Valence (chemistry)Condensed matter physicsCyanideMetals and AlloysAnalytical chemistryPhotomagnetic effectGeneral ChemistryCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundchemistryThermalMaterials ChemistryCeramics and CompositesIrradiationLaser lightdescription
The self-assembly of [Fe(III)(Tp)(CN)(3)](-) and [Fe(II)(bik)(2)(S)(2)](2+) affords the cyanide-bridged mixed valence {Fe(III)(2)Fe(II)(2)}(2+) molecular square, which exhibits a photomagnetic effect under laser light irradiation at low temperature and also shows thermal spin-state conversion near ambient temperature.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2012-05-03 | Chemical Communications |