Novel unsymmetrical ortho-metalated dirhodium (II) catalysts: trans influence of the axial ligand

6533b827fe1ef96bd1286e9a

RESEARCH PRODUCT

Novel unsymmetrical ortho-metalated dirhodium (II) catalysts: trans influence of the axial ligand

Salah‐e. Stiriba Pascual Lahuerta M. Angeles Ubeda Julia Pérez-prieto

subject

Ligand Trans effect Group (periodic table)Chemistry Organic Chemistry Drug Discovery Reactivity (chemistry)Biochemistry Medicinal chemistry Catalysis

description

Inductive effects of an X axial group which are transmitted through the RhRh bond influence the reactivity of ortho-metalated dirhodium complexes 3 in the cyclization of 1-diazo-5-penten-2-one (4).

year	journal	country	edition	language
1999-02-01	Tetrahedron Letters

https://doi.org/10.1016/s0040-4039(98)02682-3

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