ChemInform Abstract: Synthesis of a Tetraazido-Substituted 2-Tetrazene from 1,5- Cyclooctadiene and Iodine Azide.

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RESEARCH PRODUCT

ChemInform Abstract: Synthesis of a Tetraazido-Substituted 2-Tetrazene from 1,5- Cyclooctadiene and Iodine Azide.

Herbert Meier Bernd Rose Dieter Schollmeyer

subject

chemistry.chemical_compound chemistry Cyclooctene Tetrazene 1 5-Cyclooctadiene chemistry.chemical_element Hydrochloric acid General Medicine Azide Nonane Iodine Medicinal chemistry

description

In contrast to the addition of iodine azide to cyclooctene (1) or 1,3-cyclooctadiene (5), its reaction with 1,5-cyclooctadiene (12) leads mainly to the surprisingly stable tetraazido-substituted 2-tetrazene 14 The structure of this was established by 15N-NMR studies and an X-ray structural analysis. Treatment of 14 with hydrochloric acid yields the diazido-substituted 9-azabicyclo[3.3.1]nonane 20.

year	journal	country	edition	language
2010-08-03	ChemInform

https://doi.org/10.1002/chin.199728117

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