6533b827fe1ef96bd12870ce
RESEARCH PRODUCT
EIS and Ac-electrogravimetry study of PB films in KCl, NaCl, and CsCl aqueous solutions
And Michel KeddamDavid Giménez-romeroJosé Juan García-jareñoFrancisco VicenteHubert PerrotClaude Gabriellisubject
Prussian blueAqueous solutionChemistryAnalytical chemistryQuartz crystal microbalanceElectrochemistrySurfaces Coatings and FilmsDielectric spectroscopychemistry.chemical_compoundElectrogravimetryElectrodeMaterials ChemistryPhysical and Theoretical ChemistryElectrical impedancedescription
Prussian Blue films have been studied by means of ac-electrogravimetry, electrochemical impedance spectroscopy, and electrochemical quartz crystal microbalance in different aqueous salt solutions. Impedance data was interpreted in terms of a model based on a potential drop at the electrode/film interface and a potential drop at the film/solution interface. Quantitative results obtained by the fitting of impedance and ac-electrogravimetry allow to conclude that the main contribution to the potential drop at the film/solution interface is due to the dehydration-hydration process of cations on entering or leaving the film.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2003-09-17 |