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RESEARCH PRODUCT

Stoichiometric Control of the Magnetic Properties in Copper( II ) Cyano‐Bridged Bimetallic Complexes

Francisco M. RomeroVíctor SánchezCarlos Giménez-saizAlicia NuezEugenio Coronado

subject

Inorganic ChemistryFerromagnetismChemistryInorganic chemistrychemistry.chemical_elementPhysical chemistryCopperBimetallic stripStoichiometryIon

description

Control of the Cu2+ ion coordination environment affords a 1D, magnetically diluted compound, [Cu(cis-chxn)2]3[Fe(CN)6]2·7H2O (1) and the 2D ferromagnetic material [Cu(cis-chxn)]3[Fe(CN)6]2·6H2O (2) with a critical temperature, Tc, of 3.5 K. (© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003)

https://doi.org/10.1002/ejic.200300641