6533b828fe1ef96bd1287871

RESEARCH PRODUCT

ChemInform Abstract: Intramolecular Michael Reaction of tert-Butylsulfinyl Ketimines: Asymmetric Synthesis of 3-Substituted Indanones.

Pablo BarrioLidia HerreraElsa RodríguezAmparo AsensioMiguel A. MaestroSantos Fustero

subject

ChemistryIntramolecular forceReagentMichael reactionEnantioselective synthesisGeneral MedicineBase (exponentiation)Medicinal chemistry

description

The reaction proceeds in the presence of the Ruppert—Prakash reagent (Tms-CF3) with either TBAT or TBAF as a base.

https://doi.org/10.1002/chin.201215086