6533b828fe1ef96bd1287a45

RESEARCH PRODUCT

Photoinduced HS state in the first spin-crossover chain containing a cyanocarbanion as bridging ligand

Sébastien PilletSmail TrikiJean Sala-palaJean-françois LétardCarlos J. Gómez-garcíaMathieu MarchivieGaelle DupouyClaude Lecomte

subject

Cyanocarbanion ligandsChemistryStereochemistryUNESCO::QUÍMICAPolimeryc approachMetals and AlloysBridging ligandBridging ligandGeneral ChemistryState (functional analysis)UNESCO::QUÍMICA::Química macromolecular:QUÍMICA [UNESCO]CatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsChain (algebraic topology)Polimeryc approach ; Cyanocarbanion ligands ; Photoinduction ; Bridging ligandSpin crossoverPhotoinductionMaterials ChemistryCeramics and Composites:QUÍMICA::Química macromolecular [UNESCO]

description

A new polymeric approach, based on cyanocarbanion ligands, for the design of spin crossover (SCO) compounds led us to the compound [Fe(abpt)2(tcpd)] (1) (tcpd^2 = (C[C(CN)2|3)^2 , abpt = 4-amino-3,5-bis(pyridin-2-yl)-1,2,4-triazole) which has been characterised as the first SCO molecular chain involving a cyanocarbanion as bridging ligand. Gomez Garcia, Carlos Jose, Carlos.Gomez@uv.es

yearjournalcountryeditionlanguage
2009-06-09
http://hdl.handle.net/10550/16730