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RESEARCH PRODUCT
Synthesis of a Tetraazido-Substituted 2-Tetrazene from 1,5-Cyclooctadiene and Iodine Azide
Dieter SchollmeyerBernd RoseHerbert Meiersubject
15-CyclooctadieneOrganic Chemistrychemistry.chemical_elementHydrochloric acidGeneral ChemistryIodineMedicinal chemistrychemistry.chemical_compoundchemistryCycloocteneTetrazeneOrganic chemistryAzidePhysical and Theoretical ChemistryNonanedescription
In contrast to the addition of iodine azide to cyclooctene (1) or 1,3-cyclooctadiene (5), its reaction with 1,5-cyclooctadiene (12) leads mainly to the surprisingly stable tetraazido-substituted 2-tetrazene 14 The structure of this was established by 15N-NMR studies and an X-ray structural analysis. Treatment of 14 with hydrochloric acid yields the diazido-substituted 9-azabicyclo[3.3.1]nonane 20.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1997-02-01 | Liebigs Annalen |