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RESEARCH PRODUCT
The first authenticated example of triorganotin(IV) perchlorate complexes of some heterocyclic bases
Eleonora RivarolaDebashis DeyD. D. MishraW.l. BasaiawmoitT. S. Basu Baulsubject
InfraredChemistryStereochemistryOrganic ChemistryIonic bondingNuclear magnetic resonance spectroscopyBiochemistryInorganic ChemistryTrigonal bipyramidal molecular geometryPerchloratechemistry.chemical_compoundCrystallographyElemental analysisMössbauer spectroscopyPyridineMaterials ChemistryPhysical and Theoretical Chemistrydescription
Abstract A convenient method is reported for the synthesis of some novel complexes of composition (R 3 SnL 2 ) ClO 4 where L represents pyridine, γ-picoline, 2,2′-bipyridine and 1,10-phenanthroline; and R n Bu or Ph. All of the new ionic complexes have been characterized by elemental analysis, molar conductance, infrared, multinuclear nuclear magnetic resonance ( 1 H, 13 C and 119 Sn) and 119 Sn Mossbauer spectroscopies. The complexes of composition (R 3 SnL 2 )ClO 4 exist both in solution and in the solid state with trans -trigonal bipyramidal structure where the R-groups occupy the equatorial positions while the ligands are in the axial position.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1993-03-01 | Journal of Organometallic Chemistry |