6533b828fe1ef96bd1288441
RESEARCH PRODUCT
Light induced charging of polymer functionalized nanorods.
Hans-jürgen ButtMatthias ZornRudolf ZentelRiidiger BergerWolfgang TremelStefan A. L. WeberMuhammed Nawaz Tahirsubject
chemistry.chemical_classificationKelvin probe force microscopeMaterials scienceMechanical EngineeringBioengineeringNanotechnologyGeneral ChemistryPolymerCondensed Matter PhysicsFluorescencechemistryChemical engineeringMicroscopyCopolymerMoietySurface modificationGeneral Materials ScienceNanoroddescription
ZnO nanorods were functionalized with new block copolymers containing a hole transporting moiety in one block and a dye and an anchor system in the second block. After functionalization, the ZnO nanorods are well dispersible in organic media and the fluorescence of the dye is quenched. Kelvin probe force microscopy was used to measure changes in electrical potential between the ZnO nanorod and the polymeric corona. Upon light irradiation, potential changes on the order of some tens of millivolts were observed on individual structures. This effect is attributed to light-induced charge separation between the ZnO nanorod and its hole transporting polymeric corona.
year | journal | country | edition | language |
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2010-08-12 | Nano letters |