6533b828fe1ef96bd1288a49

RESEARCH PRODUCT

A magnetic look into the protecting layer of Au

Agrachev MikhailAntonello SabrinaDainese TizianoGascón José APan FangfangRissanen KariRuzzi MarcoVenzo AlfonsoZoleo AlfonsoMaran Flavio

subject

Chemistry

description

We prepared four structurally related paramagnetic Au25(SR)018 clusters. 1H ENDOR and NMR signals could be successfully related to the types of ligand and the distance of protons from the central gold core. It is shown that the unpaired electron can be used as a very precise probe of the structure of the interface between metal core and capping ligands.

yearjournalcountryeditionlanguage
2016-08-17Chemical science
10.1039/c6sc03691khttps://pubmed.ncbi.nlm.nih.gov/28567262