6533b828fe1ef96bd1288c84
RESEARCH PRODUCT
Increasing the nuclearity and spin ground state in a new family of ferromagnetically-coupled {Ni10} disk-like complexes bearing exclusively end-on bridging azido ligands
Theocharis C. StamatatosTheocharis C. StamatatosJasmin KrauseDimitris I. AlexandropoulosEva RentschlerLuca M. Carrellasubject
Bridging (networking)010405 organic chemistryChemistryBruciteMetal ions in aqueous solutionMetals and AlloysGeneral Chemistryengineering.material010402 general chemistry01 natural sciencesCatalysis0104 chemical sciencesSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsIonCrystallographyMaterials ChemistryCeramics and CompositesengineeringGround statedescription
The synthesis of a new family of ferromagnetically-coupled {Ni10} clusters counterbalanced by various [Ln(NO3)5]2− ions is herein described. The resulting compounds are organic chelate-free and the metal ions are exclusively bridged by end-on azido ligands to stabilize a beautiful disk-like topology reminiscent of the structure of the brucite mineral.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2018-01-01 | Chemical Communications |