6533b828fe1ef96bd1288dbd
RESEARCH PRODUCT
Crystal structure of bis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-κ2N2,N3]bis(thiocyanato-κS)copper(II)
Lahcen El AmmariSalaheddine GuesmiAbdelhakim LaachirMohamed SaadiFouad Bentisssubject
crystal structureStereochemistrychemistry.chemical_elementThio-Crystal structure010402 general chemistry010403 inorganic & nuclear chemistry01 natural sciencesChlorideResearch CommunicationsMetalchemistry.chemical_compoundmedicine25-bis(pyridin-2-yl)-134-thiadiazoleGeneral Materials Sciencecopper complexCoordination geometrythiocyanate ligandCrystallographyHydrogen bondGeneral Chemistrythiocyanate ligandCondensed Matter PhysicsCopper0104 chemical sciencesCrystallographychemistryQD901-999visual_artvisual_art.visual_art_mediumDiazole25-bis(pyridin-2-yl)-134-thiadiazolemedicine.drugdescription
The structure of the title compound is similar to that of the related complexes [Co(C12H8N4S)2(N3)2] and [Ni(C12H8N4S)2(N3)2] in which the azide ion is substituted by the thiocyanate group. The CuN4S2 octahedron is more distorted than the CoN6 and NiN6 octahedra.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2016-07-01 | Acta Crystallographica Section E Crystallographic Communications |