6533b828fe1ef96bd1288e54

RESEARCH PRODUCT

Crystal structure of tricarbon­yl(N-di­phenyl­phosphanyl-N,N′-diisopropyl-P-phenyl­phospho­nous di­amide-κ2 P,P′)cobalt(I) tetra­carbonyl­cobaltate(−I) toluene 0.25-solvate

Laura DuraAnke SpannenbergTorsten Beweries

subject

crystal structureCrystallographyChemistryHydrogen bondmetallacycleTricarbonchemistry.chemical_elementGeneral ChemistryCrystal structureMetallacycleCondensed Matter PhysicsTolueneMedicinal chemistrycobaltResearch Communicationsphosphine ligandchemistry.chemical_compoundQD901-999AmideGeneral Materials ScienceCobaltCoordination geometry

description

The title compound {Co(CO)3[Ph2PN(i-Pr)P(Ph)N(H)i-Pr]}[Co(CO)4] is an ionic species consisting of a Co(CO)3[Ph2PN(i-Pr)P(Ph)N(H)i-Pr] cation and a [Co(CO)4] anion.

10.1107/s1600536814024908http://europepmc.org/articles/PMC4257381