Modelling electric field control of the spin state in the mixed-valence polyoxometalate [GeV14O40]8−

6533b828fe1ef96bd1288ea7

RESEARCH PRODUCT

Modelling electric field control of the spin state in the mixed-valence polyoxometalate [GeV14O40]8−

Juan M. Clemente-juan Alejandro Gaita-ariño Eugenio Coronado Salvador Cardona‐serra Nicolas Suaud Nicolas Suaud Ondrej Svoboda Ondrej Svoboda

subject

Valence (chemistry)Spins Spin states Condensed matter physics Chemistry Metals and Alloys 02 engineering and technology General Chemistry Electron 010402 general chemistry 021001 nanoscience & nanotechnology 01 natural sciences Catalysis 0104 chemical sciences Surfaces Coatings and Films Electronic Optical and Magnetic Materials Delocalized electron Paramagnetism Electric field Polyoxometalate Materials Chemistry Ceramics and Composites Condensed Matter::Strongly Correlated Electrons [CHIM.OTHE]Chemical Sciences/Other 0210 nano-technology

description

International audience; : The two-electron reduced mixed-valence polyoxometalate [GeV14O40](8-) presents an unusual paramagnetic behaviour as a consequence of the partial trapping of these electrons. The effect of applying an electric field is that of inducing antiferromagnetic coupling between the two delocalized electronic spins.

year	journal	country	edition	language
2013-09-10	Chemical Communications

https://doi.org/10.1039/c3cc44859b

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