6533b828fe1ef96bd12890e2
RESEARCH PRODUCT
Chlorido(2,2′-{[2-(1-methyl-1H-imidazol-2-yl-κN 3)imidazolidine-1,3-diyl-κN]bis(methylene)}bis(1-methyl-1H-imidazole-κN 3))copper(II) perchlorate
Marciela ScarpelliniDiego S. Padilhasubject
crystal structureCrystallographyCopper(II) perchlorate010405 organic chemistrychemistry.chemical_elementGeneral ChemistryCrystal structure010402 general chemistryCondensed Matter Physics01 natural sciencesMedicinal chemistryCopper0104 chemical sciencesPerchloratechemistry.chemical_compoundchemistryQD901-999ImidazolidineImidazoleMoietyGeneral Materials Scienceimidazolidine ligandEne reactioncopper complexdescription
In the crystal structure of the title complex, [CuCl(C17H24N8)]ClO4, the copper(II) metal exhibits an N4Cl pentacoordinate environment in a distorted square-pyramidal geometry. Coordination to the metal centre occurs through the three 1-methylimidazole N atoms from the pendant groups, one amine N atom from the imidazolidine moiety and one chlorido anion. Intermolecular interactions take place at two of the 1-methyl-imidazole rings in the form of parallel-displaced π–π stacking interactions forming chains parallel to the a axis. Three O atoms of the perchlorate anion are rotationally disordered between two orientations with occupancies of 0.5.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2019-05-01 | Acta Crystallographica Section E Crystallographic Communications |