6533b829fe1ef96bd1289a6b

RESEARCH PRODUCT

High affinity of "arbor" iron porphyrins for dioxygen

Bruno AndriolettiRoger GuilardBernard BoitrelDavid Ricard

subject

inorganic chemicals010405 organic chemistryChemistryMaterials Chemistry[CHIM]Chemical SciencesCarbon monoxide bindingGeneral Chemistry010402 general chemistry01 natural sciencesMedicinal chemistry[ CHIM ] Chemical SciencesCatalysis0104 chemical sciences

description

International audience; The equilibrium rates of dioxygen and carbon monoxide binding have been measured for a series of capped iron porphyrins called "arbor". The affinity for dioxygen of these models is 100-fold higher than the highest previously reported values.

https://hal-univ-rennes1.archives-ouvertes.fr/hal-01469622