6533b829fe1ef96bd1289b03

RESEARCH PRODUCT

Coordination polymers undergoing spin crossover and reversible ligand exchange in the solid

M. Carmen MuñozJosé RealAna Galet

subject

PolymersUNESCO::QUÍMICACrystallographic data:QUÍMICA [UNESCO]CatalysisIonSynthesisSpin crossoverMaterials ChemistryTopology (chemistry)chemistry.chemical_classificationLigandUNESCO::QUÍMICA::Química analíticaMetals and AlloysGeneral ChemistryPolymerX-Ray crystallographicSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsCoordination ; Polymers ; Synthesis ; NbO topology ; X-Ray crystallographicCrystallographychemistryCoordination:QUÍMICA::Química analítica [UNESCO]Ceramics and CompositesNbO topologyNatural bond orbital

description

Here we report the synthesis and characterisation of a polymer made up of a system of parallel 2-D grids of Fe(II) ions linked by [Au(CN)2]– bridges and its transformation into a new system of three interpenetrated 3-D coordination open frameworks with the NbO topology. Reversibility of this crystal-to-crystal transformation is evidenced by X-ray crystallographic data and from their spin crossover properties. Real Cabezos, Jose Antonio, Jose.A.Real@uv.es

yearjournalcountryeditionlanguage
2006-10-19
10.1039/b606434ehttp://hdl.handle.net/10550/16799