6533b829fe1ef96bd128a207
RESEARCH PRODUCT
A novel photochemical 1,4-acyl migration in enol esters. The photolysis of enol acetates of 3-phenylpropiophenones
J. PrimoaMercedes AlvaroV. BaldoviHermenegildo GarcíaMiguel A. Mirandasubject
chemistry.chemical_classificationDiketoneKetoneCarboxylic acidOrganic ChemistryPhotodissociationPhotochemistryBiochemistryEnolHomolysischemistry.chemical_compoundchemistryDrug DiscoveryAliphatic compoundBond cleavagedescription
Abstract Photolysis of the enol acetates 1a,b gives the 1,4-diketones 4a,b by a mechanism involving a primary homolytic carbonyl—oxygen bond cleavage, followed by 1,2-hydrogen shift and in cage recombination.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1987-01-01 | Tetrahedron Letters |