6533b829fe1ef96bd128a256

RESEARCH PRODUCT

1,6-π-Electrocyclization of 3-Vinyl-FunctionalizedN,N-Dimethyl-2,2′-Bisindolyl: Some analysis of the educt transformation process

Ulf PindurY.-s. Kim

subject

ChemistryComputational chemistryScientific methodOrganic ChemistryProton NMRReactivity (chemistry)IsomerizationTransformation (music)

description

The thermally and photochemically induced 1,6-π-electrocyclization reaction of 3-vinyl-functionalized N, N'-dimethyl-2,2′-bisindolyls 4 has been analysed and some reactivity aspects are presented. On the basis of time dependent 1H nmr and uv spectroscopic measurements the educt transformations can be observed in detail. Some results of the isomerization process of the educts are also given.

https://doi.org/10.1002/jhet.5570350118