Reactions of azoesters and dimethyl acetylenedicarboxylate with 3-methyl-1,2,4-triazole-5-thione

6533b829fe1ef96bd128acdc

RESEARCH PRODUCT

Reactions of azoesters and dimethyl acetylenedicarboxylate with 3-methyl-1,2,4-triazole-5-thione

Aldo Palazzo Carmelo La Rosa Gaetano Giammona Bianca Carlisi Maria Neri

subject

Dimethyl acetylenedicarboxylate Diethyl azodicarboxylate chemistry.chemical_compound Azo compound chemistry Organic Chemistry Disulfide bond 1 2 4-Triazole Medicinal chemistry

description

The addition of dimethyl acetylenedicarboxylate to 3-methyl-1,2,4-triazole-5-thione (1), both in alcoholic medium and in inert solvents, has been investigated. When 1 was allowed to react with diethyl azodicarboxylate a disulfide 5 was obtained.

year	journal	country	edition	language
1991-02-01	Journal of Heterocyclic Chemistry

https://doi.org/10.1002/jhet.5570280221

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