6533b829fe1ef96bd128ae3c
RESEARCH PRODUCT
Structure of doped polyaniline - dielectric spectroscopy measurements
R. Diaz CallejaE.s. Matveevasubject
ChemistryDopingGeneral Physics and AstronomyDissociation (chemistry)Dielectric spectroscopychemistry.chemical_compoundAdsorptionImpurity[PHYS.HIST]Physics [physics]/Physics archivesElectric fieldPolymer chemistryPolyanilinePhysical chemistryDielectric lossdescription
The role of doping reagents (residual water and acid anions) in determining the electric properties of a chemically synthesized polyaniline (PANI) was studied using a dielectric spectroscopy method. Dependencies of dielectric losses and susceptibility of PANI as the functions of temperature (-100÷+100°C) and electric field frequency (0.3÷30000 Hz) were examined at it was shown the role of water acts as a doping impurity similar to acid anions. The model is proposed to explain the role of water in terms of adsorption of H 2 O molecules at nitrogen sites of PANI chain and their dissociation
year | journal | country | edition | language |
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1993-11-01 | Le Journal de Physique IV |