6533b829fe1ef96bd128b015

RESEARCH PRODUCT

One-Pot, Clean Synthesis of Vanillic Acid from Ferulic Acid

Yi-jun XuRiccardo DelisiFrancesco ParrinoMario PagliaroLeonardo PalmisanoRosaria Ciriminna

subject

010405 organic chemistryChemistryoxidationChemistry (all)General Chemistry010402 general chemistry01 natural sciences0104 chemical sciencesCatalysisFerulic acidchemistry.chemical_compoundvanillinYield (chemistry)Vanillic acidvanillic acidOrganic chemistrySettore CHIM/07 - Fondamenti Chimici Delle Tecnologiebismuth tungstateferulic acid

description

Ferulic acid dissolved in water is selectively oxidized to vanillic acid in high yield (≈60 %) under remarkably mild and green conditions, namely at room temperature with air as primary oxidant, over a catalytic amount of nanostructured Bi2WO6. The process is general and opens the route to the selective oxidation of natural substances into derivatives of significant applicative relevance.

10.1002/slct.201600111https://dx.doi.org/10.1002/slct.201600111