Slow magnetic relaxation in carbonato-bridged dinuclear lanthanide(iii) complexes with 2,3-quinoxalinediolate ligands

6533b82afe1ef96bd128b8aa

RESEARCH PRODUCT

Slow magnetic relaxation in carbonato-bridged dinuclear lanthanide(iii) complexes with 2,3-quinoxalinediolate ligands

Emilio Pardo Julia Vallejo Oscar Fabelo Laura Cañadillas-delgado Francesc Lloret Miguel Julve Joan Cano Isabel Castro

subject

Lanthanide chemistry.chemical_classification Ligand Chemistry Inorganic chemistry Metals and Alloys General Chemistry Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Ion Coordination complex Crystallography Magnet Materials Chemistry Ceramics and Composites Magnetic relaxation

description

The coordination chemistry of the 2,3-quinoxalinediolate ligand with different lanthanide(iii) ions in basic media in air affords a new family of carbonato-bridged M 2 III compounds (M = Pr, Gd and Dy), the Dy 2 III analogue exhibiting slow magnetic relaxation behaviour typical of single-molecule magnets. This journal is © 2012 The Royal Society of Chemistry.

year	journal	country	edition	language
2012-06-30	Chemical Communications

https://doi.org/10.1039/c2cc33674j

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