Cietvielu luminoforu molekulārais dizains

6533b82afe1ef96bd128c6d5

RESEARCH PRODUCT

Cietvielu luminoforu molekulārais dizains

Artūrs Mazarevičs

subject

FOSFORESCENCE STARPMOLEKULĀRAS MIJIEDARBĪBAS PHOSPHORESCENCE ORGANISKIE SAVIENOJUMI LUMINISCENCE Ķīmija

description

Cietvielu luminoforu molekulārais dizains. Mazarevičs A., zinātniskie vadītāji Mg. chem. Leduskrasts K., Prof., Dr. chem. Sūna E. Maģistra darbs, 72 lapaspuses, 44 attēli, 11 tabulas, 38 literatūrās avoti, 1 pielikums. Latviešu valodā. Literatūras apskatā analizēti organiskie luminofori, luminiscence un fosforescence. Iekļauti organiskās fosforescences iegūšanas metožu piemēri izmantojot starpmolekulāru mijiedarbību veidošanu, smagā atoma efektu, kā arī heteroatomu ievadīšanu molekulā. Rezultātu izvērtējumā aprakstīta sintezēto savienojumu iegūšana un analizētas to luminiscentās īpašības. Eksperimentālajā daļā sintezēti 26 savienojumi, no kuriem luminiscentās īpašības noteiktas 13. No luminiscentajiem savienojumiem, četri satur arilgredzenu piektajā pozīcijā tiofēna ciklā, trīs alkilķēdes tiofēna ciklā ceturtajā un piektajā pozīcijā, trīs satur karbazola grupu tiofēna cikla trešajā pozīcijā un karbonilfragmentu otrajā pozīcijā, bet trīs – benzo[b]tiofēnu, kā arī karbazola un karbonilfragmentu attiecīgi trešajā un otrajā tiofēna cikla pozīcijā. Eksperimentālajā daļā ir apskatītas sintēžu metodes, kā arī doti vielu raksturojumi, izmantojot 1H KMR, 13C KMR, IS un EA analīzes metodes.

year	journal	country	edition	language
2022-01-01

https://dspace.lu.lv/dspace/handle/7/59456

PEPhysical Sciences and Engineering
- PE2Fundamental Constituents of Matter
  - PE2_1Theory of fundamental interactions
  - PE2_2 Phenomenology of fundamental interactions
  - PE2_3Experimental particle physics with accelerators
  - PE2_4Experimental particle physics without accelerators
  - PE2_6Nuclear, hadron and heavy ion physics
  - PE2_8Gas and plasma physics
  - PE2_5Classical and quantum physics of gravitational interactions
  - PE2_7Nuclear and particle astrophysics
  - PE2_9 Electromagnetism
  - PE2_10Atomic, molecular physics
  - PE2_11Ultra-cold atoms and molecules
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  - PE2_17Metrology and measurement
  - PE2_16Non-linear physics
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LSLife Sciences
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  - LS2_8Proteomics
  - LS2_9Metabolomics
  - LS2_10Glycomics/Lipidomics
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  - LS2_12Biostatistics
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- LS4Physiology in Health, Disease and Ageing
  - LS4_1Organ and tissue physiology and pathophysiology
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- LS5Neuroscience and Disorders of the Nervous System
  - LS5_1Neuronal cells
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SHSocial Sciences and Humanities
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