6533b82bfe1ef96bd128d745

RESEARCH PRODUCT

Preparation, characterization and hydrolytic degradation of PLA/PCL co-mingled nanofibrous mats prepared via dual-jet electrospinning

Roberto ScaffaroLuigi BottaFrancesco Lopresti

subject

Co-mingled nanomatCo-electrospinningMaterials scienceHydrolytic degradationPolymers and PlasticsScanning electron microscopeGeneral Physics and Astronomy02 engineering and technology010402 general chemistry01 natural sciencesContact anglechemistry.chemical_compoundPhysics and Astronomy (all)Polymer degradationUltimate tensile strengthMaterials ChemistryComposite materialchemistry.chemical_classificationPolymers and PlasticpH dependent degradationOrganic ChemistryPolymerBuffer solutionPolymer degradation021001 nanoscience & nanotechnologyElectrospinning0104 chemical scienceschemistryChemical engineeringDual-jet electrospinningWetting0210 nano-technology

description

Abstract PLA/PCL co-mingled nanofibrous mats were prepared via multi-jet electrospinning. The concentration of PLA and PCL in the co-mingled mats were controlled by changing the flow rate of the two polymer solutions. The amount of PLA and PCL in the co-mingled nanofibrous mats was monitored by UV–Vis measurements through a colored dye added to PLA and by FTIR-ATR analysis. Morphology and mechanical properties of the nanofibrous mats were respectively examined by scanning electron microscopy (SEM) and tensile tests. Water contact angles measurements were also carried out in order to investigate the wettability of the materials. Finally, the hydrolytic degradation of the mats in buffer solution at pH 4, pH 7 and pH 10 were studied up to 50 days.

10.1016/j.eurpolymj.2017.09.016http://hdl.handle.net/10447/242331