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RESEARCH PRODUCT
A Co2O2 metallacycle exclusively supported by l-valine
Carlos Martí-gastaldoJosé Ramón Galán-mascarósA. Murcia-martínezsubject
chemistry.chemical_classificationChemistryStereochemistryMetal ions in aqueous solutionBioinorganic chemistryGeneral ChemistryMetallacycleCondensed Matter PhysicsAmino acidValineHydrothermal synthesisGeneral Materials ScienceChirality (chemistry)Group 2 organometallic chemistrydescription
Abstract [Co2(OH)2( l -valine)4]·2.5H2O has been prepared under hydrothermal conditions and constitutes the first example of a [Co2O2] core supported exclusively by aminoacids. This synthetic dimetallic model for redox active metalloenzymes is one of the few binary aminoacid compounds of biologically relevant metal ions that has been structurally characterized, showing the possibilities of this synthetic approach for preparation of models in bioinorganic chemistry.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2008-12-01 | Solid State Sciences |