6533b82cfe1ef96bd128e914
RESEARCH PRODUCT
Reaction of 2H-1-benzothiete with diazo compounds in the presence of rhodium(II) acetate
Herbert MeierDieter Gröschlsubject
chemistry.chemical_compoundRhodium(II) acetatechemistryOrganic ChemistryDrug DiscoveryOrganic chemistryDiazoBiochemistryCatalysisdescription
2,3-Dihydrobenzo[b]thiophenes (7a-e) were prepared by the Rh2+ catalyzed reaction of 2H-1-benzothiete (1) and diazo compounds (3a-e). α,β-Unsaturated diazo esters (3b,e) and diazo ketones (3d,e) yielded additionally 4,5-dihydro-1-benzothiepins (11b,c) and 5H-4,1-benzoxathiepins (12d,e), respectively.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 1995-08-01 | Tetrahedron Letters |