6533b82cfe1ef96bd128e941

RESEARCH PRODUCT

Synthesis and Properties of Some Simple Organotitanium Compounds

Manfred T. Reetz

subject

chemistry.chemical_compoundMaterials sciencechemistryComputational chemistrySimple (abstract algebra)Reactivity (chemistry)Thermal stabilityPhenylmagnesium bromideBond energySelectivityBond-dissociation energyCarbanion

description

Before embarking on a detailed discussion of the titanation of carbanions, synthetic and physical organic aspects of several typical organotitanium (IV) compounds shall be surveyed, including thermal stability, aggregation state, X-ray structural data and bond energies. Some of this information is useful in understanding reactivity and selectivity in reactions with organic substrates. Low valent Ti (II) and Ti (III) shall be mentioned only on passing; the interested reader is referred to reviews [1].

yearjournalcountryeditionlanguage
1986-01-01
https://doi.org/10.1007/978-3-642-70704-9_2