Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis

6533b82cfe1ef96bd128eb28

RESEARCH PRODUCT

Diastereomeric control of enantioselectivity: evidence for metal cluster catalysis

Amrendra K. Singh Matti Haukka Ebbe Nordlander Ahmed F. Abdel-magied Michael G. Richmond

subject

intact Ligand Stereochemistry Metals and Alloys Enantioselective synthesis Diastereomer Tiglic acid General Chemistry hydrogenation catalysis Catalysis Surfaces Coatings and Films Electronic Optical and Magnetic Materials Catalysis Metal chemistry.chemical_compound chemistry visual_art Materials Chemistry Ceramics and Composites visual_art.visual_art_medium Cluster (physics)triruthenium clusters ta116

description

Enantioselective hydrogenation of tiglic acid effected by diastereomers of the general formula [(μ-H)2Ru3(μ3-S)(CO)7(μ-P–P*)] (P–P* = chiral Walphos diphosphine ligand) strongly supports catalysis by intact Ru3 clusters. A catalytic mechanism involving Ru3 clusters has been established by DFT calculations. peerReviewed

year	journal	country	edition	language
2014-06-06	Chemical Communications

10.1039/c4cc02319f http://juuli.fi/Record/0028747214

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