6533b82cfe1ef96bd128ebcb

RESEARCH PRODUCT

Light-induced decarboxylation in a photo-responsive iron-containing complex based on polyoxometalate and oxalato ligands.

Yan DuanJuan M. Clemente-juanEugenio CoronadoCarlos Giménez-saizJoão C. Waerenborgh

subject

LigandDecarboxylation02 engineering and technologyGeneral Chemistry010402 general chemistry021001 nanoscience & nanotechnologyPhotochemistry01 natural sciencesOxalate0104 chemical scienceschemistry.chemical_compoundElectron transferChemistrychemistryIntramolecular forceMössbauer spectroscopyPolyoxometalate0210 nano-technologyDerivative (chemistry)

description

A new iron-oxalato polyoxometalate exhibits a remarkable photocoloration effect in the solid state based entirely on an intramolecular process.

10.1039/c6sc01919fhttps://pubmed.ncbi.nlm.nih.gov/30294411