6533b82cfe1ef96bd128ec79
RESEARCH PRODUCT
A novel high-spin heterometallic Ni12K4cluster incorporating large Ni–azide circles and an in situ cyanomethylated di-2-pyridyl ketone
Xiao-ming ChenSusumu KitagawaMasaaki OhbaJuan Modesto Clemente JuanMing-liang TongMontserrat MonfortXian He Busubject
In situPotassium tert-butylateKetoneBase (chemistry)UNESCO::QUÍMICAPotassiumchemistry.chemical_elementCyanomethylation of ketone:QUÍMICA [UNESCO]Ferromagnetically-coupled Mll-azideCatalysisCatalysischemistry.chemical_compoundPolymer chemistryMaterials ChemistryCluster (physics)Organic chemistrySpin (physics)Novelchemistry.chemical_classificationUNESCO::QUÍMICA::Química inorgánicaMetals and AlloysNickel acetateGeneral Chemistry:QUÍMICA::Química inorgánica [UNESCO]Cyanomethylation of ketone ; Potassium tert-butylate ; Ferromagnetically-coupled Mll-azide ; Nickel acetate ; NovelSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialschemistryCeramics and CompositesAzidedescription
Reaction of di-2-pyridyl ketone (dpk) with nickel acetate and azide in the presence of potassium tert-butylate as a catalytic base generates the title compound, which contains the largest [Ni(m1,1-N3)]6 circles in the discrete ferromagnetically-coupled MII–azide cluster family, and shows an unprecedented in situ cyanomethylation of ketone. Clemente Juan, Juan Modesto, Juan.M.Clemente@uv.es
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2005-02-23 | Chem. Commun. |