6533b82cfe1ef96bd128f35d

RESEARCH PRODUCT

[Bis(dimethylsulphoxide) protium][trans-bisdimethylsulphoxidetetrachloroiridate(III)]

Jussi ValkonenE.r.j. SillanpaaP.s. CartwrightRobert D. Gillard

subject

HydrogenChemistryStereochemistrychemistry.chemical_elementNuclear magnetic resonance spectroscopyCrystal structureMedicinal chemistrySulfurRhodiumInorganic ChemistryBond lengthX-ray crystallographyMaterials ChemistryIridiumPhysical and Theoretical Chemistry

description

Abstract [(DMSO)2H]trans-[IrCl4(DMSO)2] (DMSO = dimethylsulphoxide) has been structurally characterized. The hydrogen bonded cation [DMSOHDMSO]+ has a very short OHO bond distance (2.405 A) which compares well with that in the known rhodium analogue. The two DMSO ligands are trans on iridium and coordinate via the sulphur atoms. Earlier work had assigned the cis structure to the anion in this compound.

yearjournalcountryeditionlanguage
1988-01-01Polyhedron
https://doi.org/10.1016/s0277-5387(00)81793-3