6533b82cfe1ef96bd128f44b
RESEARCH PRODUCT
Synthesis and structural studies of TiRu polymetallic systems
Pierre Le GendreClaude MoïsePhilippe Richardsubject
Inorganic Chemistrychemistry.chemical_compoundchemistryStereochemistryDimerOrganic ChemistryMaterials Chemistrychemistry.chemical_elementPhysical and Theoretical ChemistryBiochemistryMedicinal chemistryRutheniumdescription
Abstract The reaction of the titanocene monophosphines 1 and 2 with the dimer [( p -cymene)RuCl 2 ] 2 give the heterobimetallic compounds ( p -cymene)[(η 5 -C 5 H 4 )(μ-η 5 :η 1 -C 5 H 4 PPh 2 )TiCl 2 ]RuCl 2 and ( p -cymene)[(η 5 -C 5 H 4 )(μ-η 5 :η 1 -C 5 H 4 CH 2 CH 2 PPh 2 )TiCl 2 ]RuCl 2 , respectively. Both structures have been confirmed by X-ray diffraction. By using same procedure, the synthesis of a trimetallic complex RuTiRu has been achieved.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2000-07-01 | Journal of Organometallic Chemistry |