6533b82cfe1ef96bd1290162
RESEARCH PRODUCT
Aminobisphenolate supported tungsten disulphido and dithiolene complexes
Anssi PeuronenReijo SillanpääPia DamlinAri LehtonenEsko SalojärviHenri Kiveläsubject
Models MolecularInorganic chemistryMolecular Conformationchemistry.chemical_elementOxidestungsten disulphidoCrystal structureSulfidesTungstenElectrochemistryTungstenInorganic ChemistryDiethyl acetylenedicarboxylatechemistryReagentPolymer chemistryElectrochemistryHydroxybenzoatesOrganometallic Compoundsdithiolene complexesta116description
Dioxotungsten(vi) complexes with tetradentate amino bisphenolates were converted into the corresponding Cs-symmetric amino bisphenolate disulphido complexes by a reaction with either Lawesson's reagent or P2S5. Further reaction with diethyl acetylenedicarboxylate leads to the formation of diamagnetic tungsten(iv) dithiolene compounds. The syntheses, crystal structures, spectroscopic and electrochemical characterization of such disulphido and dithiolene complexes are presented.
| year | journal | country | edition | language |
|---|---|---|---|---|
| 2015-04-28 | Dalton Transactions |